From a supramolecular tetranitrile to a porous covalent triazine-based framework with high gas uptake capacities.
نویسندگان
چکیده
Transformation of tetra(4-cyanophenyl)ethylene under Lewis acidic (ZnCl2) conditions at 400 °C leads to the formation of a porous covalent triazine-based organic framework (CTF) with a high surface area (2235 m(2) g(-1)), high CO2 and CH4 uptakes and the highest hydrogen uptake for a CTF material (1.86 wt% at 77 K, 1 bar).
منابع مشابه
A triazine-based covalent organic polymer for efficient CO2 adsorption.
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عنوان ژورنال:
- Chemical communications
دوره 49 38 شماره
صفحات -
تاریخ انتشار 2013